Thermodynamics — MEEN 315

Derivation

Since a reversible cycles could be constructed such that $\sigma_{ab}=0,\>\sigma_{cb}=0$ then

$$ \int_1^2(\frac{\delta Q}{T})_a=\int_1^2(\frac{\delta Q}{T})_c $$

and so we can define an extensive property, entropy, whose change is given by

$$ S_2-S_1=\int_1^2(\frac{\delta Q}{T})_{rev} $$

Further, this renders a differential equation which will produce two $Tds$ equations, which serve as the basis for many of our derivations.

$$ \delta Q_{rev}=TdS $$

$$ \delta Q_{rev}=dU+\delta W_{rev}=dU+pdV $$

$$ Tds=du+pdv $$

$$ dH=dU+pdV+Vdp $$

$$ Tds=dh-vdp $$

Applications of Differential Entropy Equations

Considering a change in phase from saturated liquid to saturated vapor

$$ p=c, T=c\Rarr ds=\frac{dh}{T} $$

$$ s_g-s_f=\frac{h_g-h_f}{T} $$

Considering an incompressible liquid

$$ du=c_TdT,\>v=c\Rarr ds=\frac{c_TdT}{T} $$

$$ s_2-s_1=\int_{T_1}^{T_2}\frac{c_T}{T}dT $$

$$ c_T=const $$

$$ s_2-s_1=c_T\ln\frac{T_2}{T_1} $$

Ideal Gases

The change in entropy of an ideal gas may be calculated using specific heats and pressures or volumes, however, these calculations are already completed, and may be used by referencing $s^o(T)$ tables. Alternatively, we may assume constant specific heats to simplify the calculations

$$ Tds=du+pdv,\>du=c_vdT,\>p=\frac{RT}{v} $$

$$ \Delta s=\int_1^2\frac{c_v(T)}{T}dT+R\ln\frac{v_2}{v_1} $$

$$ Tds=dh-vdp,\>dh=c_pdT,\>v=\frac{RT}{p} $$

$$ \Delta s=\int_1^2\frac{c_p(T)}{T}dT+R\ln\frac{p_2}{p_1} $$